Those were done last weekend. It was fine. I just stood upwind and took care to not stick my face in it and held my breath when I smelled the zinc. Between the 6" beams and 14" electrodes I never really had an arc going long enough for it to be a problem.
I was lying in bed that night thinking to myself "gee, I feel fine right now is this gonna hit me at 3am?" and started googling zinc poisoning which really freaked out the woman I was sleeping with.
Having disposable pads for your starts and stops is SOP for "shit that matters". I don't see how galv or zinc or other surface coating would make a difference.
My understanding is that the far edges of the flange are the least stressed and that it shouldn't be a big deal. I can always sit the thing on its side and build it up then grind it back down.
Also, while we're on the subject.
Does anyone know if there's any structural benefit to grinding the welds flush?