Pinions aren't horizontal. Front is whatever it's at with I think +6* caster. Rear is something, no idea. I think it was close to parallel with t-case output at some point, but I think it's pointed up a bit more now. It's a trail only rig so I wasn't as concerned as I would be with a streetable rig.
I did some digging on caliper alternatives to match up with the iBooster. I converted to 8x6.5 with my 2007 SD60, and it looks like easiest rotor to move to is the 1999 E350 rear, which is 1.19" thickness. I did some looking for other vehicles that ran the same thickness rotor to see what might be a good match. Here's what I came up with, first is what the Accord brakes are capable of, then my current setup, and then some choices to go with the 1.19" rotor.
Caliper, area, hydraulic ratio, brake torque
1999 Accord Front, 8.16 in^2, 10:1, 26799 in#
2007 F250 D60, 17.49in^2, 18:1, 30210 in#
2004 F250 Rear, 9.62 in^2, 12:1, 34975 in#
2000 Ford Explorer, 10.29 in^2, 13:1, 37212 in#
2009 Ford Flex, 10.98 in^2, 13:1, 39504 in#
2019 Buick Enclave, 10.98 in^2, 13:1, 39504 in#
So I think I'll look to see if Flex or Enclave calipers are cheaper, and likely go that route. I think the 13:1 pedal will be livable after my 18:1 current setup I've had. All of the options are fixed dual piston calipers.